First, there is no 3.5 D&D sheet by Roll20, but based on the screenshot it looks like you are using the D&D 3.5E sheet by Diana P. Second, 3.5 doesn't usually have an effect for wearing helmets, so it isn't going to be in most sheets armor section. If you are using a house rule where helmets do something atypical my suggestion would be to create a note of it somewhere, or depending on the sheet make it a modifier to an existing item like your armor.