From the Roll20 Wiki: If an inline roll contains a crit success, it will be highlighted with a
green box. If there's a crit failure, it's highlighted in red. If it
has both (because there was more than one roll), it's in blue. Also when
you mouse-over the inline roll to see the details of the roll, it'll
show red and green highlights for the rolls themselves for
crits/fumbles. Check the inline roll's tooltip.