Hrmm I am happy to help new DM's get their feet wet, and it is definitely a daunting task at first. There are a few things that you should always keep in mind as far as I know, and these things you will learn pretty harshly sometimes if you aren't prepared. 1. Don't over prepare your encounters/story... try to keep it general in your notes, but let the intricacies play out in game. Nothing is worse than spending 8 hours coming up with a story just to have players blow right by it without understanding it's importance, or by circumventing your plan somehow. 2. This is not DM vs. Players. I have seen quite a few DM's that have went down that path. That being said, don't be a total pushover either. You need to learn the balance with your group and what they are capable of. Some players like difficult dungeons where death is always around the corner, some prefer the intricacies of your story. Trying to keep a balance between the two is difficult, but talking to your players as a previous person said can make all the difference. 3. Probably the most important, make sure you get enough rest and eat BEFORE the game. Being tired can make you forget things, slow down the game, and make you cranky, avoid that if at all possible. 4. Try to be decisive. If there is a rules question that has little bearing on the outcome of the game, make a fair ruling and stick with it. If you find out later that your ruling was incorrect, THESE THINGS HAPPEN. Explain how you were incorrect to your players, and how it actually works, that way if the situation ever rises again not only you know, but your players also understand the ruling difference. This allows you to continue the game without having to break all the time for rulings, just do what you think is right. Without writing a book, I will end there, there are too many nuances to DMing to post lots of stuff here. Use the internet to your advantage, it is probably the DM's greatest tool now, besides a great imagination. It is a daunting task to be a DM, but your players enjoyment is almost always worth it, and the positives usually far outweigh the negatives.